Please find below data from the School Capacity Collection 2010 (national/LA and school level):

To view the CSV files, right-click on the link, select 'save as' and save the file onto your computer. You'll then be able to open it using Excel.

• 2010 School Capacity Collection Metadata specification
  This document describes the data contained in the 2010 school level capacity files, which contain a breakdown of school places by primary and secondary schools.
• Maintained Primary School data (csv file, 1.1MB)
• Maintained Primary School data (Excel file, 2.5MB)
• Maintained Secondary School data (csv file, 217KB)
• Maintained Secondary School data (Excel file, 515MB)
• Statistical Release Report, Schools Capacity 2010 (pdf, 50KB)
• LA Level and Academies data (Excel file, 240KB)

This data is also available on the DfE website: http://www.education.gov.uk/rsgateway/DB/STR/d000982/index.shtml